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Episode 1 - Mr. Right on Purpose

Desperate to escape her brother-in-law’s harassment, Brynn impulsively marries a stranger after one blind date. Turns out, her new husband is billionaire Alec Rhodes—and their “chance” meeting was anything but accidental. She thought she rushed into marriage. She was the woman he’d spent years loving, waiting for, and finally making his.

Episode 2 - Mr. Right on Purpose

Lin Zhixia has long been harassed by her creep of a brother-in-law, Zhou Qiang. Desperate to escape her difficult situation and move out of the Lin family home, she decides to find a flash-marriage partner through a matchmaking agency. To her surprise, her blind-date match turns out to be the exceptionally charismatic Shen Yanci. In reality, Shen Yanci is the richest man in Shangjing who has been secretly in love with Lin Zhixia for years. He has meticulously orchestrated this encounter by buying the matchmaking agency and intentionally flat-tires his car to accidentally "run into" her and pick up her lost pendant. Faced with Lin Zhixia's urgent request to get married as soon as possible, Shen Yanci readily agrees. The two immediately head to the civil affairs bureau to register their marriage, kicking off a contract marriage where his true identity remains hidden.

Episode 3 - Mr. Right on Purpose

To escape her perverted brother-in-law Zhou Qiang, Lin Zhixiahurriedly enters a flash marriage with a stranger, Shen Yanzhi, at the Civil Affairs Bureau. After getting their marriage certificate, the two act distant, and Lin Zhixia leaves first under the pretext of submitting an assignment at Nancheng University. Shen Yanzhi then has his assistant, Chen Mo, accept a public finance lecture invitation at Nancheng University that he had declined for three years, admitting it is for his newlywed wife. At school, Lin Zhixia faces ostracism from classmates due to her striking looks. Meanwhile, Shen Yanzhi arrives in a high-profile manner as the CEO of the Beijing Group to teach the class, and Lin Zhixia is shocked to discover in the crowd that this powerful man from the capital is none other than the flash-marriage husband she just wed.

Episode 4 - Mr. Right on Purpose

In this episode, Lin Zhixia, a student at Nancheng University, has a chance encounter on campus with her secret flash-marriage husband, Shen Yanci, the supreme power figure of Shangjing. Facing a husband with a vastly different social status who is adored by everyone, Zhixia feels insecure and tries to avoid him by pretending they are strangers. Sensing her avoidance, Yanci mistakenly believes she wants to keep their relationship hidden. Later, during a highly anticipated finance lecture at the university auditorium, Yanci deliberately calls Zhixia up to the stage as his sole partner for a demonstration in front of all the faculty and students, instantly shattering her plan to keep their marriage a secret.

Episode 5 - Mr. Right on Purpose

During a lecture at Nancheng University, Shen Yanci, who holds the dual identity of Beijing’s richest man and a specially appointed professor, publicly called upon Lin Zhixia to come to the stage and solve a difficult problem. Overwhelmed by nervousness, Lin Zhixia blanked out and found herself in an awkward predicament, facing cold sneers and mockery from her classmates. At this critical moment, Shen Yanci intimately interacted with her in front of everyone, taking her hand and personally guiding her to complete the formula, causing a sensation throughout the auditorium. In private, looking at the embarrassed Lin Zhixia, Shen Yanci's heart was filled with deep doting affection for his newlywed wife, while Lin Zhixia felt completely at a loss amidst the hostile questioning of her classmates.

Episode 6 - Mr. Right on Purpose

In this episode, Lin Zhixia faces hostility and interrogation from her classmates due to her close proximity to President Shen at school, and she manages to escape by making up an excuse about a wrong formula. Shortly after, she receives a call from the hospital informing her that her older sister, Lin Zhiqui, has suffered a worsening heart condition, prompting her to rush to the hospital in deep anxiety. Inside the hospital room, her despicable brother-in-law, Zhou Qiang, takes advantage of Lin Zhiqui's unconscious state to verbally and physically harass Lin Zhixia, even using her sister's medical expenses as leverage to attempt a sexual assault. As Lin Zhixia desperately fights back and threatens to call the police, the standoff reaches a critical point when Lin Zhiqui wakes up weakly in her hospital bed, witnessing the ugly scene.

Episode 7 - Mr. Right on Purpose

This episode centers on the internal and external crises faced by Lin Zhixia while her sister, Lin Zhiqiuh, is gravely ill. Zhou Qiang openly harasses Zhixia in the hospital room, only to disguise himself as a caring family member the moment Zhiqiuh wakes up. Zhiqiuh suffers a heart attack and vomits blood, and the doctor warns that she cannot take any emotional shocks. This leaves Zhixia, who wants to expose Zhou Qiang, caught in a dilemma. On her deathbed, Zhiqiuh entrusts Zhixia to Zhou Qiang's care, and Zhou Qiang seizes the opportunity to reveal his lecherous nature. Upon returning to the Zhou household, the mother-in-law, old Mrs. Zhou, is even more harsh. Not only does she curse the dying Zhiqiuh as a bad omen, but she also uses a 200,000-yuan bride price as leverage to force Zhixia into a "proxy marriage" into the Zhou family after her sister's death.

Episode 8 - Mr. Right on Purpose

This episode depicts Lin Zhixia's miserable plight and a turning point in her despair. As Lin Zhiqiu lies gravely ill, Old Mrs. Zhou and her son Zhou Qiang reveal their true, ugly colors, forcing Zhixia to marry her brother-in-law Zhou Qiang as a replacement after her sister's death. Zhixia leaves home in anger, only to find herself penniless with nowhere to go. On a stormy night, driven to desperation, she goes to the Shen Group headquarters, trying to find her newlywed "stranger husband," Shen Yanzi. Just as she is about to leave, feeling out of place and lacking an appointment, she unexpectedly bumps into Shen Yanzi.

Episode 9 - Mr. Right on Purpose

Driven out into the pouring rain by Zhou Qiang and his mother, Lin Zhixia wanders the streets in misery before arriving at the Jing Corporation, where she accidentally runs into Shen Yanzhi, who is on his way to a meeting. Seeing her drenched and heartbroken, Shen not only refuses to turn her away, but publicly takes off his suit jacket and drapes it over her shoulders. Upon learning that she is looking for a place to stay and considering a flash marriage, Shen dominantly declares, "I will support you," and carries her home in his arms, completely ditching a multi-hundred-million-dollar project meeting. Back at the Shen family mansion, Zhixia is stunned by the sheer luxury, while Shen's subsequent seductive gestures quickly heat up the ambiguous tension between them.

Episode 10 - Mr. Right on Purpose

Lin Zhixia takes shelter from the rain at Shen Yanci's home, where she feels deeply embarrassed, mistakenly assuming his bare chest is intentional, while he is actually just avoiding discomfort from his own wet clothes. As they share a subtly romantic atmosphere, Zhixia changes into Shen's white shirt and receives a video call from her elder sister, Zhiqiiu. Her frail sister asks why she ran away from home, but her brother-in-law, Zhou Qiang, suddenly bursts into the frame. Feigning concern while making veiled threats, Zhou sharply notices Shen Yanci standing behind Zhixia, and a confrontation is on the verge of breaking out.

Episode 11 - Mr. Right on Purpose

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